These are both so hard!

1. Naoto
2. Yosuke
3. Kanji
4. Nanako
5. Rise

1. Elsa
2. Rapunzel
3. Genie
4. Belle
5. Basil

Pokemon (both humans and pokemons)

... How can I choose just 5 from 721!

Sorry. ;;

Ok, humans are a bit easier at least (Though I'm sad I had to drop Yellow, Bianca, Winona... and a bunch of others. This is mostly by manga+games.)

1. N
2. White/Hilda
3. Platinum
4. Wally
5. Looker

1. Eevee
2. Umbreon
3. Starmie (one of my first competitively trained Pokemon... and it was great!)
4. Mew
5. Butterfree

I feel like such a genwunner or whatever they were called... though to be fair the last two slots could be filled with any of maybe 30 Pokemon.