有点想念之前陪我吃晚餐的美珊,她毕业了,自己就得自己吃。
Bulk P.=thermal hot spots cause degradation & discolouration & chain transfer broadens the molecular weight distributions.
Emulsion P.=no unreacted monomer leftover,no thermal hot spot form
initiator conc.high(more peroxides,persulfates) can lower the molecular weight polymer,radical conc.,rate of termination.
Propagation=monmer migrates fr large monomer droplets to the micelles to sustain polymerization.
Initiation=when an initiator fragment migrates into a micelle & react with a monomer molecule.